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Low-temperature growth of high-Tc superconducting films by plasma-enhanced metal-organic chemical vapor deposition
Authors:Keiichi Kanehori  Nobuyuki Sugii  Shin'Ichiro Saito
Affiliation:Central Research Laboratory , Hitachi, Ltd. , Kokubunji, Tokyo, 185, Japan
Abstract:Plasma-enhanced MOCVD in which metal-organic compounds are sublimated directly into the growth chamber is studied for the first time as a new low-temperature process for growing superconducting YBa2Cu3O--x thin films. Y(THD)3, Ba(THD)2, Cu(THD)2 and oxygen are used as metal sources and oxydizing agent. Emission spectroscopy reveals that activated metal-organic compounds and activated oxygen species are present during film growth. Superconducting YBa2Cu3O7-x films whose zero-resistivity temperature are 50 K and 82 K are grown at 550°C and 600°C.
Keywords:Oxide superconductor  YBa2Cu3O x   MOCVD  plasma  thin film
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