Sequence‐Dependent Photocurrent Generation through Long‐Distance Excess‐Electron Transfer in DNA |
| |
Authors: | Dr. Shih‐Hsun Lin Prof. Dr. Mamoru Fujitsuka Prof. Dr. Tetsuro Majima |
| |
Affiliation: | The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Osaka, Japan |
| |
Abstract: | Given its well‐ordered continuous π stacking of nucleobases, DNA has been considered as a biomaterial for charge transfer in biosensors. For cathodic photocurrent generation resulting from hole transfer in DNA, sensitivity to DNA structure and base‐pair stacking has been confirmed. However, such information has not been provided for anodic photocurrent generation resulting from excess‐electron transfer in DNA. In the present study, we measured the anodic photocurrent of a DNA‐modified Au electrode. Our results demonstrate long‐distance excess‐electron transfer in DNA, which is dominated by a hopping mechanism, and the photocurrent generation is sequence dependent. |
| |
Keywords: | DNA electrochemistry electron transfer photochemistry thin films |
|
|