| 可逆加成-断裂链转移(RAFT)聚合在星形聚合物合成中的应用 |
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| 引用本文： | 张鹏,潘毅,郑朝晖,丁小斌,彭宇行. 可逆加成-断裂链转移(RAFT)聚合在星形聚合物合成中的应用[J]. 高分子通报, 2009, 0(4) |
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| 作者姓名： | 张鹏 潘毅 郑朝晖 丁小斌 彭宇行 |
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| 作者单位： | 1. 中国科学院成都有机化学研究所,成都,610041;中国科学院研究生院,北京,100049
2. 中国科学院成都有机化学研究所,成都,610041 |
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| 摘 要： | 可逆加成-断裂链转移(RAFT)聚合作为一种新型活性自由基聚合,由于其具有单体适用面广、操作条件温和、实施聚合的方法多--本体、溶液、乳液、悬浮聚合均可的优点已经在分子设计方面取得了广泛的应用.星形聚合物作为一种特殊结构的聚合物,由于其具有较低的结晶度、较小的流体动力学体积等独特的性质,越来越引起研究者的重视.本文综述了近几年来采用RAFT法合成星形聚合物的研究进展.根据合成星形聚合物所用的RAFT多官能团试剂种类,对RAFT法合成星形聚合物的反应进行了分类.
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| 关 键 词： | 可逆加成-断裂链转移(RAFT) 星形聚合物 活性自由基聚合 |
Progress of Reversible Addition-Fragmentation Chain Transfer(RAFT) Polymerization Applied to the Synthesis of Star Polymers |
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| ZHANG Peng,PAN Yi,ZHENG Zhao-hui,DING Xiao-bin,PENG Yu-xing. Progress of Reversible Addition-Fragmentation Chain Transfer(RAFT) Polymerization Applied to the Synthesis of Star Polymers[J]. Polymer Bulletin, 2009, 0(4) |
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| Authors: | ZHANG Peng PAN Yi ZHENG Zhao-hui DING Xiao-bin PENG Yu-xing |
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| Affiliation: | 1.Chengdu Institute of Organic Chemistry;Chinese Academy of Sciences;Chengdu 610041;China;2.Graduate School of the Chinese Academy of Sciences;Beijing 10049;China |
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| Abstract: | As a new living radical polymerization,reversible addition-fragmentation chain transfer (RAFT) polymerization has lots of advantages,such as a wide range of monomers,a mild reaction condition. And RAFT polymerization can proceed in bulk,solution,emulsion and suspension polymerization. So RAFT polymerization has exhibited wide applications in molecular design. Due to their unique characters,such as low crystallinity,smaller volume of fluid dynamics,star polymers as a special structure polymer have attracted ... |
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| Keywords: | RAFT Star polymer Living radical polymerization |
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