3-Aroylmethyl derivatives of 2(1H)quinoxalinone and 2H-l,4-benzoxazin-2-ones existing in the enamine form |
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Authors: | Yasuo Iwanami Takeshi Inagaki |
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Abstract: | Seventeen derivatives of 2(1H)quinoxalinone and 2H-l,4-benzoxazin-2-one have been synthesized for structural study. All of the compounds having a substituted phenacyl, isonicotinoylmethyl, or 2-furoylmethyl side chain are shown to exist in the enamine form with an internal chelation both in the crystalline and solution states as evidenced by the ir and pmr spectra, respectively. In the gas phase, however, o-hydroxyphenacyl derivatives can exist in another type of intramolecularly hydrogen-bonded form which is supported by their mass spectra. |
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