Combined CI-HY studies of atomic states. IV. The four lowest 1S and four lowest 1P states of He and the lowest 1S and 1P states of H−1

Combined CI -HY method calculations are reported for the ground and first three excited S states of He with an error on the order of 10^?7 a.u. within the same 120-term basis. For He ¹P, the four lowest states are obtained with an error ≤2 × 10^?6 a.u. within the same 102-term basis. H^?1 S and ¹P states are also treated by the same CI -HY technique. The utility of an spd Slater-type orbital, r, v = 0, 1 basis is investigated, with indications that it might be an excellent basis for states of first row atoms.