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由乙二胺四乙酸合成一类新型的N,N′-二羧甲基大环醚双内酯和大环胺双内酰胺
引用本文:秦圣英. 由乙二胺四乙酸合成一类新型的N,N′-二羧甲基大环醚双内酯和大环胺双内酰胺[J]. 有机化学, 1984, 0(4)
作者姓名:秦圣英
作者单位:四川大学化学系 成都
摘    要:EDTA脱水成二酐后,与多缩乙二醇或α,ω-二胺反应,分别得到了大环醚双内酯(Ⅰ—Ⅳ)和大环胺双内酰胺(Ⅴ—Ⅷ)。各产物的结构均经红外、核磁、分子量和元素分析鉴定。

关 键 词:EDTA  冠醚  合成

Synthesis of a Series of New N,N''''-Dicarboxymethyl Macrocyclic Ether-bislactones and Amine-bislactams Derived from EDTA
Qin Shengying. Synthesis of a Series of New N,N''''-Dicarboxymethyl Macrocyclic Ether-bislactones and Amine-bislactams Derived from EDTA[J]. Chinese Journal of Organic Chemistry, 1984, 0(4)
Authors:Qin Shengying
Affiliation:Qin Shengying Department of Chemistry Sichuan University,Chengdu
Abstract:This paper reports the synthesis of a series of new N,N'-dicarboxymethylmacrocyclic ether-bislactones and amine-bislactams.The EDTA dianhydride reacted withpolyethylene glycol [HOCH_2CH_2(OCH_2CH_2)_nOH n=0,1,2,3] or alkylene diamine[H_2NCH_2(CH_2)_mNH_2 m=1,2,3] to give the title compounds,which have beencharacterised by IR,~1H NMR,molecular weight determination and elemental analvsis.
Keywords:EDTA  crown ether compound  synthesis.  
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