| HYDROLYSIS TRANSFORMATION OF A POLYSTYRENE—b—POLY（tert—BUTYL ACRYLATE） COPOLYMER AND MICELLIZATION PROPERTIES OF THE HYDROLYZED COPOLYMER |
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| 引用本文： | SIZhihuai LIHexian 等.HYDROLYSIS TRANSFORMATION OF A POLYSTYRENE—b—POLY（tert—BUTYL ACRYLATE） COPOLYMER AND MICELLIZATION PROPERTIES OF THE HYDROLYZED COPOLYMER[J].反应性高分子(英文版),2001,10(2):121-126. |
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| 作者姓名： | SIZhihuai LIHexian |
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| 作者单位： | The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin, China 300071
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| 摘 要： |
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| 关 键 词： | 共聚物 聚苯乙烯 丙烯酸盐 聚合反应 |
HYDROLYSIS TRANSFORMATION OF A POLYSTYRENE-b-POLY(tert-BUTYL ACRYLATE)COPOLYMER AND MICELLIZATION PROPERTIES OF THE HYDROLYZED COPOLYMER |
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| SI Zhihuai,LI Hexian,WANG Guochang,YUAN Jialong,HE Binglin.HYDROLYSIS TRANSFORMATION OF A POLYSTYRENE-b-POLY(tert-BUTYL ACRYLATE)COPOLYMER AND MICELLIZATION PROPERTIES OF THE HYDROLYZED COPOLYMER[J].Chinese Journal of Reactive Polymers,2001,10(2):121-126. |
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| Authors: | SI Zhihuai LI Hexian WANG Guochang YUAN Jialong HE Binglin |
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| Institution: | The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin, China 300071 |
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| Abstract: | A very mild and extremely efficient hydrolysis method for transformation of polystyrene-b-poly(tert-butyl acrylate)(PS-b-PtBA)to polystyrene-b-poly(acrylic acid)(PS-b-PAA) was designed and carried out using more convenient and inexpensive chlorotrimethylsilane/sodium iodide as reagents.The hydrolysis product can self-assemble in aqueous media to give regular micelles with PS block forming the core and PAA block forming the corona,or in tetrahydrofuran (THF) to give reverse micelles with the hydrophilic block in the core. |
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| Keywords: | Polystyrene-b-poly(acrylic acid) Hydrolysis Self-assembly |
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