Copper-induced N-N bond cleavage results in an octanuclear expanded-core grid-like complex |
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| Authors: | White Nicholas G Kitchen Jonathan A Joule John A Brooker Sally |
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| Institution: | Department of Chemistry and MacDiarmid Institute for Advanced Materials and Nanotechnology, University of Otago, PO Box 56, Dunedin 9054, New Zealand. |
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| Abstract: | Reaction of copper(I) acetate and 4-amino-3,5-di(2-pyridyl)-1,2,4-triazole (adpt) in methanol under ambient conditions yields octanuclear Cu(II)(8)(dpt)(4)(OH)(4)(OAc)(8)]; OAc = acetate anion, and dpt(-) = anion of deaminated adpt, 3,5-di(2-pyridyl)-1,2,4-triazolate. However, reaction of copper(ii) acetate with dptH gives tetranuclear Cu(II)(4)(dpt)(2)(OH)(OMe)(OAc)(4)]. |
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