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Electron transfer reactions of cytochrome c at metal electrodes
Authors:Song -Cheng Sun  David E Reed  John K Cullison  Lyman H Rickard  Fred M Hawkridge
Institution:(1) Department of Chemistry, Virginia Commonwealth University, Box 2006, 23284 Richmond, VA, USA;(2) Department of Physical Sciences, High Point College, 27262 High Point, NC, USA
Abstract:The heterogeneous electron transfer reactions of cytochromec occurring at platinum, gold and mercury electrodes are shown to be quasi-reversible. In each case the electrodes have not been modified and the cytochromec samples are native. This work extends previous work and demonstrates that biological molecule electron transfer reactions can be studied at clean metal surfaces to gain fundamental knowledge of the mechanisms of these reactions.
Keywords:cytochromec  metal electrodes  electron transfer
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