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Wide-band EPR spectroscopy of YAlO3: Tm3+ single crystals
Authors:G R Asatryan  A P Skvortsov  G S Shakurov
Institution:1621. Ioffe Physical-Technical Institute, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia
2621. Zavoisky Physical-Technical Institute, Kazan Scientific Center of the Russian Academy of Sciences, ul. Sibirskii trakt 10/7, Kazan, 420029, Republic of Tatarstan, Russia
Abstract:The YAlO3: Tm3+ single crystal has been studied on a wide-band EPR spectrometer. The EPR spectra of Tm3+ ions in the frequency range of 90–160 GHz have been detected for the first time. It has been confirmed that thulium ions substitute the position of Y3+ in the crystal lattice. The detected spectra have been described with the use of a spin Hamiltonian with the effective spin S = 1/2. A comparative analysis of the orientation of the magnetic axes of the Tm3+ paramagnetic center with earlier data on other rare-earth ions has been performed.
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