A systematic study of carboxylic acids in negative ion mode electrospray ionisation mass spectrometry providing a structural model for ion suppression |
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Authors: | Clifford Mike N Lopez Violeta Poquet Laure Williamson Gary Kuhnert Nikolai |
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Affiliation: | School of Biomedical and Molecular Sciences, The University of Surrey, Guildford, Surrey GU2 7XH, UK. |
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Abstract: | We report a systematic investigation of the effects and structural requirements for ion suppression in negative ion mode electrospray ionisation mass spectrometry of a series of carboxylic acids and present a structural model rationalising ion suppression effects. |
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