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THERMODYNAMIC STUDY ON THE Sm-Ba-Cu-O SYSTEM
Authors:XING XIAN-RAN  QIAO ZHI-YU  WEI SHOU-KUN  CHEN XIAO-LONG  LIANG JING-KUI and RAO GUANG-HUI
Abstract:The assembly for EMF measurement with CaF2 single crystal or MgO partially stabilized zirconia as solid state electrolyte has been constructed. From the EMF data, the standard Gibbs energies, standard enthalpies of formation and standard entropies of sir complex oxides in the Sm-Ba-Cu-O system were calculated. The decomposition pressures of these complex oxides were derived.
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