The azaphilic addition of organometallic reagents on tetrazines: scope and limitations |
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| Authors: | Já nos Faragó ,Gitta Schlosser,Andrá s Kotschy |
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| Affiliation: | a Department of General and Inorganic Chemistry, Eötvös Loránd University, Pázmány Péter s. 1/A, Budapest H-1117, Hungary
b Chemical Research Center, Hungarian Academy of Sciences, PO Box 32, H-1525 Budapest, Hungary |
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| Abstract: | A series of tetrazines were reacted with organometallic reagents. Depending on the nature of the metal azaphilic addition, reduction of the tetrazine or simple complex formation was the predominant transformation and usually high selectivity was observed. |
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| Keywords: | Tetrazines Azaphilic addition Aromatic nucleophilic substitution Reduction |
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