Cetyltrimethylammonium hydroxide (CTAOH) as a general, ecofriendly catalyst for the formation of carbon-carbon bond through nitroalkanes |
| |
| Authors: | Roberto Ballini Dennis Fiorini Maria Victoria Gil Alessandro Palmieri |
| |
| Institution: | Dipartimento di Scienze Chimiche, Università di Camerino, Via S. Agostino 1, 62032 Camerino, Italy |
| |
| Abstract: | Nitroalkanes have been found to give good yields in Michael and nitroaldol (Henry) reactions by the use of a catalytic amount (10 mol%) of CTAOH, at room temperature and under solvent free conditions and in very short reaction times. The methods do not need a large excess of the nitroalkanes and show good chemoselectivity toward further functionalities. |
| |
| Keywords: | Henry reaction Michael reaction Nitroalkanes β-Nitroalcohol CTAOH |
| 本文献已被 ScienceDirect 等数据库收录！ |
