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Novel synthesis of meso-tetraarylporphyrins using CF3SO2Cl under aerobic oxidation
Authors:Hashem Sharghi  Alireza HassaniNejad
Affiliation:Department of Chemistry, College of Science, Shiraz University, Adebiat Cross, Shiraz 71454, Iran
Abstract:meso-Tetraarylporphyrins are synthesized from pyrrole and aryl aldehydes cleanly and efficiently in one pot at room temperature using equimolar amount of CF3SO2Cl in the presence of air as oxidant. By this novel method 5,10,15,20-tetraarylporphyrins can be prepared in excellent yields.
Keywords:Porphyrin   Synthesis   Pyrrole
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