| 壳聚糖钯配位络合物的合成、表征及其催化性能研究 |
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| 引用本文： | 王岚,刘一真,刘蒲,王向宇. 壳聚糖钯配位络合物的合成、表征及其催化性能研究[J]. 离子交换与吸附, 2004, 20(6): 501-507 |
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| 作者姓名： | 王岚 刘一真 刘蒲 王向宇 |
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| 作者单位： | 郑州大学化学系,郑州,450052;郑州大学化学系,郑州,450052;郑州大学化学系,郑州,450052;郑州大学化学系,郑州,450052 |
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| 基金项目： | 2001 年度河南省高校青年骨干教师资助项目 |
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| 摘 要： | 用不同方法制备了壳聚糖钯配住络合物，并用FFIR，XPS，XRD和DTA-TG对其进行了表征，结果表明壳聚糖与钯发生配住作用形成了壳聚糖钯配位络合物，研究了该络合物对碘代笨与丙烯酸进行交叉偶联烷基化反应的催化性能，结果表明其具有良好的催化活性。
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| 关 键 词： | 壳聚糖 钯配位络合物 烷基化反应 |
| 文章编号： | 1001-5493(2004)06-0501-07 |
| 修稿时间： | 2004-05-15 |
STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYTIC PERFORMANCE OF CHITOSAN-IMMOBILIZED PALLADIUM COMPLEX |
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| WANG Lan LIU Yizhen LIU Pu WANG Xiangyu. STUDY ON SYNTHESIS,CHARACTERIZATION AND CATALYTIC PERFORMANCE OF CHITOSAN-IMMOBILIZED PALLADIUM COMPLEX[J]. Ion Exchange and Adsorption, 2004, 20(6): 501-507 |
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| Authors: | WANG Lan LIU Yizhen LIU Pu WANG Xiangyu |
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| Affiliation: | WANG Lan LIU Yizhen LIU Pu WANG Xiangyu Department of Chemistry,Zhengzhou University,Zhengzhou 450052,China |
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| Abstract: | Chitosan-immobilized palladium complex was prepared by different methods, and its structure was characterized by FTIR, XPS, XRD and DTA-TG. The results showed that chitosan had coordinated with palladium. In addition, the study on its catalytic performance for Heck arylation of acrylic acid with iodobenzene showed that the catalyst had high activity and regioselectivity for the synthesis of cinnamic acid. |
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| Keywords: | Chitosan Palladium complex Heck arylation reaction. |
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