| Esterification of Glycerol by Oleic Acid and Selective Hydrogenation of Oleic Acid Methylester Over Acid and Ru-Sn-B Supported Mesoporous AlMCM-41 |
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| 引用本文： | Qiu Bin KAN1*,J. BARRAULT2,Tong Hao WU1 1Department of Chemistry,Jilin University,Changchun 130023 2Laboratoire de Catalyse,CNRS URA 350-ESIP,40,86022 Poitiers,Cedex,France. Esterification of Glycerol by Oleic Acid and Selective Hydrogenation of Oleic Acid Methylester Over Acid and Ru-Sn-B Supported Mesoporous AlMCM-41[J]. 中国化学快报, 2001, 0(9) |
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| 作者姓名： | Qiu Bin KAN1* J. BARRAULT2 Tong Hao WU1 1Department of Chemistry Jilin University Changchun 130023 2Laboratoire de Catalyse CNRS URA 350-ESIP 40 86022 Poitiers Cedex France |
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| 作者单位： | Qiu Bin KAN1*，J. BARRAULT2，Tong Hao WU1 1Department of Chemistry，Jilin University，Changchun 130023 2Laboratoire de Catalyse，CNRS URA 350-ESIP，40，86022 Poitiers，Cedex，France |
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| 摘 要： | Demand for large pore size molecular sieves has given rise to great interests in a new family of silica-based mesoporous materials designated as M41s, which expand typical molecular sieves into an extra-large pore range and generate the potential for the applications of these materials in catalysis and sorption for very bulky molecules1-6. MCM-41 possesses a hexagonal arrangement of uniform mesopore ranging from 15 to 100 ? and can be prepared with varied Si/Al ratios. The investigations of …
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Esterification of Glycerol by Oleic Acid and Selective Hydrogenation of Oleic Acid Methylester Over Acid and Ru-Sn-B Supported Mesoporous AlMCM-41 |
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| Qiu Bin KAN,J. BARRAULT,Tong Hao WU. Esterification of Glycerol by Oleic Acid and Selective Hydrogenation of Oleic Acid Methylester Over Acid and Ru-Sn-B Supported Mesoporous AlMCM-41[J]. Chinese Chemical Letters, 2001, 0(9) |
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| Authors: | Qiu Bin KAN J. BARRAULT Tong Hao WU |
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| Affiliation: | Qiu Bin KAN1*,J. BARRAULT2,Tong Hao WU1 1Department of Chemistry,Jilin University,Changchun 130023 2Laboratoire de Catalyse,CNRS URA 350-ESIP,40,86022 Poitiers,Cedex,France |
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| Abstract: | The AlMCM-41 molecular sieves with two different pore sizes are hydrothermally synthesized in the presence of surfactants with two different chain lengths. H-AlMCM-41 and Ru-Sn-B/H-AlMCM-41 which are prepared by the conventional ion-exchange and incipient wetness techniques of the AlMCM-41 show fair catalytic activity for esterification of glycerol by oleic acid and selective hydrogenation of oleic acid methylester, respectively. |
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| Keywords: | AlMCM-41 Ru-Sn-B/H-AlMCM-41 oleic acid esterification hydrogenation. |
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