Overlapping resonances in the control of intramolecular vibrational redistribution |
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| Authors: | Gerbasi D Sanz A S Christopher P S Shapiro M Brumer P |
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| Affiliation: | Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto M5S 3H6, Canada. |
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| Abstract: | Coherent control of bound state processes via the interfering overlapping resonance scenario [Christopher et al., J. Chem. Phys. 123, 064313 (2006)] is developed to control intramolecular vibrational redistribution (IVR). The approach is applied to the flow of population between bonds in a model of chaotic OCS vibrational dynamics, showing the ability to significantly alter the extent and rate of IVR by varying quantum interference contributions. |
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