Asymmetric hydrosilylation of ketones catalysed by a chiral rhodium complex |
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| Authors: | RJP Corriu JJE Moreau |
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| Institution: | Laboratoire associé au CNRS no. 82, Laboratoire des Organométalliques, Université des Sciences et Techniques du Languedoc, 34060 - Montpellier-Cédex France |
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| Abstract: | Synthesis of optically active alkoxysilanes by asymmetric hydrosilylation of ketones, in the presence of a chiral phosphine—rhodium complex, is described; optical yields up to 46% are observed. |
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