Hydrogenation of olefins by π-arene ruthenium complexes : A role of π-arene ligand in catalytic activity |
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Authors: | R Iwata L Ogata |
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Institution: | National Chemical Laboratory for Industry, Honmachi, Shibuya-ku, Tokyo, Japan |
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Abstract: | The divalent ruthenium complexes bearing benzene, mesitylene triphenylbenzene as a π-ligand were prepared and their catalytic activity for olefin hydrogenation was examined. They showed activity in the presence of a small amount of base. Particularly, the complex with triphenylbenzene was found to have extremely high activity. Discussion here is on a role of a π-arene ligand in the activity. |
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