The formation of a reversible complex between diethylcadmium and oxygen |
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Authors: | Yu.A Alexandrov G.N Figurova G.A Razuvaev |
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Affiliation: | The Institute of Chemistry, Academy of Sciences U.S.S.R., Gorky U.S.S.R. |
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Abstract: | From an investigation of the autoxidation of diethylcadmium (DEC) in n-heptane the formation of a reversible DEC-oxygen complex has been established by a kinetic method.Some properties of this complex have been studied, viz. its ability to undergo spontaneous and catalytic transformation into bis(ethylperoxy)cadmium and its ultraviolet and infrared absorption spectra. |
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