Synthesis and some reductions of endo- and exo-3,6-epoxy-Δ4-tetrahydrophthalic anhydride |
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Authors: | T.A. Eggelte H. de Koning H.O. Huisman |
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Affiliation: | Laboratory of Organic Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, Amsterdam, The Netherlands |
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Abstract: | The synthesis of endo-3,6-epoxy-Δ4-tetrahydrophthalic anhydride from the endo-adduct of furan and maleic acid is described. Reduction of endo- and exo-3,6-epoxy-Δ4-tetrahydrophthalic anhydride with sodium borohydride gave the corresponding lactones, while catalytic hydrogenation over 10% Pd/C gave anhydride and/or hemi-acylals, depending on the solvent. |
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Keywords: | To whom all correspondence should be addressed. |
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