A novel ring substitution reaction in a cyclopentadienylruthenium phosphine complex |
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| Authors: | T Blackmore M.I Bruce F.G.A Stone R.E Davis N.V Raghavan |
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| Affiliation: | Department of Inorganic Chemistry, The University, Bristol BS8 1TS Great Britain;Department of Chemistry, Univeristy of Texas at Austin, Austin, Texas 78712 U.S.A. |
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| Abstract: | The reaction between hexafluoroacetone and Ru(PPh3)2(π-C5H5)[σ-C2(CO2Me)2H] affords a adduct, containing a coordinated ester group and an intramolecular hydrogen bond; formal insertion of (CF3)2CO into a CH bond of the cyclopentadienyl group has also occurred. |
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| Keywords: | Author to whom inquiries are to be addressed |
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