I.M. Kolthoff,P.J. Elving and F.H. Stross (Editors), Treatise on analytical chemistry. Part III. Analytical chemistry in industry : Vol. 2, Wiley-Interscience,New York, 1971, xxiv+597 pp., price £ 12.00 |
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Authors: | W.I. Stephen |
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Affiliation: | Department of Organic Chemistry, Technical University, DK-2800 LyngbyDenmark |
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Abstract: | The titration of some substituted azoles in non-aqueous solution has been studied and their relative basic strengths determined. Differentiating titration of mixtures of substituted imidazoles is only possible when one of the imidazoles is substituted with a powerful electronegative substituent, e.g. a nitro group. Azolium halides may be titrated with perchloric acid in anhydrous acetic acid after addition of mercury(II) acetate, or dissolved in acetic anhydride without addition of mercury(II) acetate; dissolved in methanol, they may be titrated as acids with tetrabutylammonium hydroxide in benzene/methanol. The acidic and basic properties of some substituted pyrazol-5-ones have been compared. |
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