Diastereomeric isomers of five-coordinate organoantimony compounds |
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Authors: | G.O. Doak J.M. Summy |
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Affiliation: | Department of Chemistry, North Carolina State University, Raleigh, North Carolina U.S.A. |
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Abstract: | A series of unsymmetrical diarylantimony trichlorides of the type PhArSbCl3, where Ar is a substituted phenyl group have been prepared. An attempt was then made to convert these to the oxides (PhArSbCl2)2O. In addition to the known compound (Ph2SbCl2)2O, only bis(phenyl-p-tolyldichloroantimony) oxide was obtained in pure form. An impure sample of bis(phenyl-p-fluorophenyldichloroantimony) oxide was also obtained. PMR spectra of the tolyl compound and 19F spectra of the fluoro compound revealed the presence of two diastereomeric forms for both compounds at low temperature. |
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