Trinuclear π-cyclopentadienyl bridging sulphido derivatives of iron |
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| Authors: | RJ Haines JA De Beer R Greatrex |
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| Institution: | Research and Process Development Department, South African Iron and Steel Industrial Corporation Limited, P.O. Box 450, Pretoria Republic of South Africa;Department of Inorganic and Structural Chemistry, The University, Leeds, LS2 9JT Great Britain |
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| Abstract: | The reaction of Fe(π-C5H5)(CO)2]2 with the dialkyl disulphides R2S2 (R = CH3, C2H5, t-C4H9 or CH2C6H5) affords, as well as dinuclear derivatives of the type Fe(π-C5H5)(CO)SR]2, trinuclear species of formula Fe3(π-C5H5)3(CO)2(S)SR]. |
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| Keywords: | Address correspondence to this author at: Department of Chemistry University of Cape Town Private Bag Rondebosch Cape Town (South Africa) |
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