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Conformation of oxygen-containing heterocycles: Search of the isomerization paths
Authors:A.A. Luggovskoy  V.G. Dashevsky  A.I Kitaigorodsky
Affiliation:Institute of Organo-Element Compounds, Academy of Sciences, Moscow USSR
Abstract:A method is proposed for the search of the conformational isomerization paths and barriers to interconversion. Use of this method in the study of the ring interconversion ofα-d-glucose gives the minimal barrier for 1C ? C 1 isomerization, which is in agreement with the experimental data.
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