Thermal studies on arsenic,antimony and bismuth alkylxanthate complexes |
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Authors: | M.A. Khwaja T.J. Cardwell R.J. Magee |
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Affiliation: | Department of Chemistry, La Trobe University, Bundoora, Melbourne, Victoria 3083 Australia |
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Abstract: | Six xanthate derivatives of arsenic(III), antimony(III), and bismuth(III) {(ROCS2)3M; R=methyl, ethyl, isopropyl, n-butyl, cyclohexyl and benzyl} have been prepared and the thermal behaviour investigated by thermogravimetry. A thermal decomposition mechanism for the complexes is proposed on the basis of the thermogravimetric data and mass spectral measurements. |
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