Structural studies in main group chemistry III. Tin-119m mössbauer investigation of some tin-nitrogen bonded compounds |
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| Authors: | P.G. Harrison J.J. Zuckerman |
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| Affiliation: | Department of Chemistry, University of Nottingham, University Park, Nottingham, NG7 2RD Great Britain;Department of Chemistry, State University of New York at Albany. 1,400, Washington Avenue, Albany, New York U.S.A. |
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| Abstract: | The tin-119m Mössbauer data are presented for several classes of organotin- nitrogen bonded compounds, including N-stannylamines, -imines, -amides, and -carbamates. Thc structures of the N,O-bis(trialkylstannyl)carbamates are discussed. Those derivatives possessing the Sn-NR-C(O)X group are intermolecularly associated via carbonyl→tin coordination, the strength of the coordination varying with X in the manner H ≈ OSnR3 > OR. |
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| Keywords: | Author to whom correspondence should be addressed. |
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