Bis{2-[dimethylamino)methyl]phenyl}silverlithium,a tetranuclear organometallic compound with bridging aryl groups between silver and lithium |
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Authors: | AJ Leusink G An Koten JW Marsman JG Noltes |
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Institution: | Institute for Organic Chemistry TNO, Utrecht The Netherlands |
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Abstract: | Bis{2-(dimethylamino)methyl]phenyl}silverlithium has been prepared and characterized. Molecular weight determinations, and 13C NMR and 1H NMR spectra reveal that the compound exists (in benzene) as a tetranuclear mixed metal cluster containing aryl groups bridging the silver and lithium atoms. Silver-proton, silver-carbon and lithium-carbon couplings have been observed in the NMR spectra of this compound. |
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