On the Reactions of Furan‐2,3‐diones with Oxindole (=1,3‐Dihydro‐2H‐indol‐2‐one) and Lawesson Reagent. Synthesis of New 1,3‐Dihydro‐2H‐indol‐2‐ones,Bis‐furanones,and Bis‐pyrrolones |
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Authors: | Elif Korkusuz ?smail Y?ld?r?m |
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Institution: | 1. Department of Chemistry, Faculty of Sciences, Erciyes University, TR‐38039 Kayseri, (phone: +90‐352‐4374901/33164;2. fax: +90‐352‐4374933) |
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Abstract: | Lactone analogues of 3‐substituted oxindoles (=1,3‐dihydro‐2H‐indol‐2‐ones) and nonbenzoid oxa‐analogous isoindigoid or nonbenzoid isoindigoid dyes were prepared by the reactions of furan‐2,3‐diones with oxindole and Lawesson reagent (Schemes 1 and 3), respectively. So, new derivatives of 2‐oxobutanoic acid, bis‐furanone, and bis‐pyrrolone, which are potentially biologically active compounds, were synthesized for the first time. |
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Keywords: | Furan‐2 3‐dione Oxindole Pyrrole‐2 3‐dione Michael addition Lawesson reagent Bathochromic shift Isoindigoid dyes |
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