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On the Reactions of Furan‐2,3‐diones with Oxindole (=1,3‐Dihydro‐2H‐indol‐2‐one) and Lawesson Reagent. Synthesis of New 1,3‐Dihydro‐2H‐indol‐2‐ones,Bis‐furanones,and Bis‐pyrrolones
Authors:Elif Korkusuz  ?smail Y?ld?r?m
Institution:1. Department of Chemistry, Faculty of Sciences, Erciyes University, TR‐38039 Kayseri, (phone: +90‐352‐4374901/33164;2. fax: +90‐352‐4374933)
Abstract:Lactone analogues of 3‐substituted oxindoles (=1,3‐dihydro‐2H‐indol‐2‐ones) and nonbenzoid oxa‐analogous isoindigoid or nonbenzoid isoindigoid dyes were prepared by the reactions of furan‐2,3‐diones with oxindole and Lawesson reagent (Schemes 1 and 3), respectively. So, new derivatives of 2‐oxobutanoic acid, bis‐furanone, and bis‐pyrrolone, which are potentially biologically active compounds, were synthesized for the first time.
Keywords:Furan‐2  3‐dione  Oxindole  Pyrrole‐2  3‐dione  Michael addition  Lawesson reagent  Bathochromic shift  Isoindigoid dyes
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