Vibrational analysis of the 1,1,1-trifluoroethyl halides |
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| Authors: | GA Crowder |
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| Institution: | Department of Chemistry and Killgore Research Center, West Texas State University, Canyon, Texas 79015 U.S.A. |
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| Abstract: | Normal coordinate calculations have been carried out for CF3CH2Cl using a 30-parameter valence force field. The resulting force constants for the CF3 group have been transferred to CF3CH2F, CF3CH2Br and CF3CH2I with excellent results. Previous vibrational assignments have been revised, the calculations showing that several of the normal modes are highly mixed. |
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