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Silica Gel‐Supported Polyphosphoric Acid (PPA/SiO2): An Efficient and Reusable Heterogeneous Catalyst for Facile Synthesis of 14‐Aryl‐14H‐dibenzo[a,j]xanthenes under Solvent‐free Conditions
Authors:Amir Khojastehnezhad  Abolghasem Davoodnia  Mehdi Bakavoli  Niloofar Tavakoli‐Hoseini  Mohsen Zeinali‐Dastmalbaf
Institution:Department of Chemistry, Faculty of Sciences, Islamic Azad University, Mashhad Branch, Mashhad, Iran
Abstract:A simple, efficient and green method for the synthesis of 14‐aryl‐14H‐dibenzoa,j]xanthenes by a one‐pot condensation reaction of β‐naphthol and aryl aldehydes using silica gel‐supported polyphosphoric acid (PPA/SiO2), an effective and reusable catalyst, under solvent‐free conditions is described. The present methodology offers several advantages, such as a simple procedure with an easy work‐up, short reaction times, high yields, and the absence of any volatile and hazardous organic solvents.
Keywords:14‐Aryl‐14H‐dibenzo[a  j]xanthenes  PPA/SiO2  heterogeneous catalysis  green chemistry  solvent‐free conditions
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