Determination of the concentration of strong acids with a permaplex membrane electrode in the presence of hydrofluoric acid and various cations |
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Authors: | Thorsten Eriksson Gillis Johansson |
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Institution: | Department of Analytical Chemistry, University of Ume·a, S 901 87 Ume·aSweden |
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Abstract: | A strongly acidic cation-exchanger membrane electrode was used to measure the concentration of nitric, hydrochloric and sulphuric acid over the range 10-3-7 N. Hydrofluoric acid interfered when its concentration approached that of the strong acid. The electrode showed selectivity for H+ over the cations Cr3+, Fe3+, Ni2+ Ag+ and K+. Measurements of the acidity could be made with a reproducibility of the order of tenths of a millivolt. It was shown that the electrode could be used for direct measurement of acidity in stainless steel pickling baths. |
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