Reactions of triethylsilyl thiophenoxide with ketones having an electron-with-drawing group on the α-carbon |
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| Authors: | Iwao Ojima Yoichiro Nagai |
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| Institution: | Sagami Chemical Research Center, 4-4-1 Nishi-Onuma, Sagamihara 229 Japan;Department of Chemistry, Gunma University, Kiryu, Gunma 376 Japan |
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| Abstract: | Triethylsilyl thiophenoxide has been found to react with easily enolizable ketones to give silyl enol ethers; these have also been synthesized by a RhI complex catalysed reaction of triethylsilane with enolizable ketones in the presence of a small amount of silyl thioether or thiophenol. |
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