Hexabromocyclopentadiene V. The Diels-Alder reaction of hexabromocyclopentadiene |
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| Authors: | RG Pews CW Roberts CR Hand TE Evans |
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| Institution: | Halogens Research Laboratory The Dow Chemical Company, Midland, Michigan 48640 U.S.A.;Analytical Research Laboratory, The Dow Chemical Company, Midland, Michigan 48640 U.S.A. |
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| Abstract: | The reactivity of hexabromocyclopentadiene (1) as a diene in the Diels-Alder reaction has been determined with a number of dienophiles. The results of the present study show that 1 behaves as an electron-poor diene in that cyclopentadiene is a more reactive dienophile than maleic anhydride. Qualitatively, 1 has been found to be a less reactive diene than hexachlorocyclopentadiene. Several new Diels-Alder adducts of 5,5-dibromo-1,2,3,4-tetrachlorocyclopentadiene are also reported. |
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| Keywords: | To whom inquiries should be addressed |
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