The synthesis of some (pentafluorophenyl)germanium compounds |
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Authors: | M.N. Bochkarev L.P. Maiorova N.S. Vyazankin |
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Affiliation: | Institute of Chemistry, U.S.S.R. Academy of Sciences, Gorky U.S.S.R. |
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Abstract: | Tris(pentafluorophenyl)germanium bromide reacts with lithium aluminium hydride or triethylgermane to give tris(pentafluorophenyl)germane. On reaction with HgR2 [where R = Et, Et3Ge and (Me3Si)2N] or reaction with diethylcadmium, the latter gave the hitherto unknown [(C6F5)3Ge]2Hg or [(C6F5)3Ge]2Cd. The germylmercurial compound could also be prepared by reaction of metallic mercury with [(C6F5)3Ge]2Cd and by exchange of bis(triethylgermyl)mercury with (C6F5)3GeBr. Some reactions of bis[tris(pentafluorophenyl)germyl]mercury are discussed. |
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