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A Theory of Electron Transfer in Bridged and Supramolecular Systems |
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| Authors: | Alexander M. Kuznetsov Jens Ulstrup |
| Affiliation: | (1) Chemistry Department, The Technical University of Denmark, Building 207, DK-2800 Lyngby, Denmark Author for correspondence E-mail |
| Abstract: | Expressions are derived for the tunnel electric current between two metals produced by the adiabatic transitions of the electrons through a bridge electron level. A new possible physical phenomenon is discussed, viz. electronically driven oscillations of the electron bridge level between two molecular wires. |
| Keywords: | bridged electrochemical contact bridged molecular wires electronically driven oscillations inverted region adiabatic electron transfer overpotential and bias voltage |
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