| 在并流交换反应器中液相水-氢同位素交换反应的研究 |
| |
| 引用本文： | 祁世纶,池东鲜,李永顺,千载虎. 在并流交换反应器中液相水-氢同位素交换反应的研究[J]. 高等学校化学学报, 1984, 5(1): 77 |
| |
| 作者姓名： | 祁世纶 池东鲜 李永顺 千载虎 |
| |
| 作者单位： | 1. 大连市光明化工研究所;2. 吉林大学计算中心, 化学系 |
| |
| 摘 要： | 本文用憎水性D型树脂为载体,铂为活性组分,使氢-液体水之间成功地进行了氢同位素的交换反应,讨论了并流反应器的动力学方程。在17.5℃、1大气压、氢的表观速度从0.04m/sec至0.1m/sec条件下,测得的催化交换反应速度常数K=34.9×103mol/m3·hr。
|
| 收稿时间： | 1982-05-24 |
A STUDY OF HYDROGEN ISOTOPE EXCHANGE BETWEEN HYDROGEN AND LIQUID WATER IN THE CONCURRENT-EXCHANGE REACTOR |
| |
| Qi Shilun,Chi Dongxian,Li Yongshun,Qian Zai hu. A STUDY OF HYDROGEN ISOTOPE EXCHANGE BETWEEN HYDROGEN AND LIQUID WATER IN THE CONCURRENT-EXCHANGE REACTOR[J]. Chemical Research In Chinese Universities, 1984, 5(1): 77 |
| |
| Authors: | Qi Shilun Chi Dongxian Li Yongshun Qian Zai hu |
| |
| Affiliation: | 1. Guangming Chemical Engineering Institute, Dalian;2. Jilin University, Changchun |
| |
| Abstract: | In this paper hydrogen exchange reaction between hydrogen and liquid water was performed successfully using hydrophobic resin of Dtype as support and Pt as active component.The kinetic equation in a concurrent flow reactor was discussed.At apparent velocity of hydrogen from 0.04m/sec to O.im/sec and 17.5℃ and under 1 atm the determined rate constant of the catalytic exchange reaction K is >30×103 mol/m3·hr. |
| |
| Keywords: | |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《高等学校化学学报》浏览原始摘要信息 |
|
点击此处可从《高等学校化学学报》下载全文 |
|
