| 直接法制备三乙氧基硅烷催化剂的研究进展 |
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| 引用本文： | 王广建,刘光彦,钟立梅,刘辉. 直接法制备三乙氧基硅烷催化剂的研究进展[J]. 化学通报, 2009, 72(8) |
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| 作者姓名： | 王广建 刘光彦 钟立梅 刘辉 |
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| 作者单位： | 青岛科技大学化工学院,青岛,266042;北京化工大学化工资源有效利用国家重点实验室,北京,100029 |
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| 基金项目： | 国家自然科学基金项目 |
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| 摘 要： | 综述了直接法合成三乙氧基硅烷的研究进展,着重对直接法的反应机理和催化剂组分的筛选进行了分析讨论.同时介绍了以三乙氧基硅烷为原料,合成烯丙基三乙氧基硅烷、γ-(2,3-环氧丙氧)丙基三乙氧基硅烷、苯乙基三乙氧基硅烷、五乙氧基二硅烷等衍生物的工艺,提出了催化剂制备过程中存在的问题及研究方向.
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| 关 键 词： | 三乙氧基硅烷 直接法 反应机理 催化剂 |
Progress of Catalyst by the Direct Synthesis of Triethoxysilane |
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| Wang Guangjian,Liu Guangyan,Zhong Limei,Liu Hui. Progress of Catalyst by the Direct Synthesis of Triethoxysilane[J]. Chemistry, 2009, 72(8) |
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| Authors: | Wang Guangjian Liu Guangyan Zhong Limei Liu Hui |
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| Affiliation: | 1School of Chemical Engineering;Qingdao University of Science and Technology;Qingdao 266042;2Beijing University of Chemical Technology;State Key Laboratory of Chemical Resource Engineering;Beijing 100029 |
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| Abstract: | The progress of preparation triethoxysilane by direct synthesis including reaction mechanism and catalyst preparation method is reviewed. The preparation methods of allyltriethoxysilane,3-methacryloxypropyltriethoxysilane,phenethyl-triethoxysilane,pentaethoxydisiloxane with triethoxysilane as raw material were mainly introduced. The current problems and future prospects of the catalysts were also discussed. |
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| Keywords: | Triethoxysilane Direct synthesis Reaction mechanism Catalyst |
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