A Dimeric η1,η5‐Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti−Ge−Ge−Ti Bond |
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| Authors: | M. Sc. Zhaowen Dong Dr. Oliver Janka Dipl.‐Ing. Jutta Kösters Dr. Marc Schmidtmann Prof. Dr. Thomas Müller |
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| Affiliation: | 1. Institut für Chemie, Carl von Ossietzky Universit?t Oldenburg, Oldenburg, Germany;2. Institut für Anorganische und Analytische Chemie, Westf?lische Wilhelms-Universit?t Münster, Münster, Germany |
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| Abstract: | Dimeric germole dianion bridged TiIII and ZrIV complexes have been synthesized. In these complexes, the germole dianion adopts a formal η1,η5 coordination to the two metal centers. The bonding situation in these bridged dimers is dominated by a covalent Ge?Ge interaction that results, for example, in a strong antiferromagnetic coupling of the d1 Ti centers. |
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| Keywords: | germole dianion magnetic properties main group chemistry titanocene X-ray diffraction |
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