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Preparation of Swellable Hydrogel‐Containing Colloidosomes from Aqueous Two‐Phase Pickering Emulsion Droplets |
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| Authors: | Dr Jean‐Paul Douliez Dr Nicolas Martin Dr Thomas Beneyton Dr Jean‐Charles Eloi Prof Jean‐Paul Chapel Dr Laurence Navailles Prof Jean‐Christophe Baret Prof Stephen Mann Dr Laure Béven |
| Institution: | 1. UMR 1332, biologie du fruit et pathologie, INRA, Univ. Bordeaux, Villenave d'Ornon, France;2. Centre for Organized Matter Chemistry and Centre for Protolife Research, School of Chemistry, University of Bristol, Bristol, UK;3. CNRS, Univ. Bordeaux, CRPP, Pessac, France;4. Chemical Imaging Facility, School of Chemistry, University of Bristol, Bristol, UK |
| Abstract: | The fabrication of stable colloidosomes derived from water‐in‐water Pickering‐like emulsions are described that were produced by addition of fluorescent amine‐modified polystyrene latex beads to an aqueous two‐phase system consisting of dextran‐enriched droplets dispersed in a PEG‐enriched continuous phase. Addition of polyacrylic acid followed by carbodiimide‐induced crosslinking with dextran produces hydrogelled droplets capable of reversible swelling and selective molecular uptake and exclusion. Colloidosomes produced specifically in all‐water systems could offer new opportunities in microencapsulation and the bottom‐up construction of synthetic protocells. |
| Keywords: | aqueous two-phase systems colloidosomes encapsulation sequestration water-in-water emulsions |