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Flexible and Hierarchical Metal–Organic Framework Composites for High‐Performance Catalysis
Authors:Dr Ning Huang  Hannah Drake  Jialuo Li  Dr Jiandong Pang  Dr Ying Wang  Shuai Yuan  Qi Wang  Peiyu Cai  Dr Junsheng Qin  Prof?Dr Hong‐Cai Zhou
Institution:1. Department of Chemistry, Texas A&M University, College Station, TX, USA;2. College of Chemistry, Tianjin Normal University, Tianjin, China
Abstract:The development of porous composite materials is of great significance for their potentially improved performance over those of individual components and extensive applications in separation, energy storage, and heterogeneous catalysis. Now mesoporous metal–organic frameworks (MOFs) with macroporous melamine foam (MF) have been integrated using a one‐pot process, generating a series of MOF/MF composite materials with preserved crystallinity, hierarchical porosity, and increased stability over that of melamine foam. The MOF nanocrystals were threaded by the melamine foam networks, resembling a ball‐and‐stick model overall. The resulting MOF/MF composite materials were employed as an effective heterogeneous catalyst for the epoxidation of cholesteryl esters. Combining the advantages of interpenetrative mesoporous and macroporous structures, the MOF/melamine foam composite has higher dispersibility and more accessibility of catalytic sites, exhibiting excellent catalytic performance.
Keywords:composite materials  heterogeneous catalysis  metal–  organic frameworks  porous materials
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