Apparent Molar Heat Capacities and Apparent Molar Volumes of Aqueous Nicotinamide at Different Temperatures |
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Authors: | Agnita Kundu Nand Kishore |
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Affiliation: | (1) Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai-400076, India |
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Abstract: | Specific heat capacities and apparent molar heat capacities of aqueous nicotinamide have been determined from 25.0 to 55.0°C using microdifferential scanning calorimetry in the molality range of 0.07433 to 1.50124 mol-kg–1. Densities and apparent molar volumes have also been determined for aqueous nicotinamide from 10.30 to 34.98°C using a digital densimeter in the molality range 0.07804–2.02435 mol-kg–1. The results of these measurements have been used to calculate the following partial molar quantities and temperature derivatives for aqueous nicotinamide as a function of temperature: Cp,2,mo, (Cp,2,mo/T)p, (2Cp,2,mo/T2)p, V2,mo, ( V2,mo/T)p, and (2V2,m2/T2)p. The results are discussed in terms of the changes in the packing of nicotinamide molecules in the crystal, interactions in the aqueous form, and its structure-promoting ability with rise in temperature. |
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Keywords: | Nicotinamide specific heat capacity partial molar heat capacity density partial molar volume |
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