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Rapid qualitative analysis of metallic alloys by electrospot chromatography
Authors:João A Medeiros  R N Damasceno
Institution:(1) Dept. of Chemistry, Catholic University, Rio de Janeiro, Brasil;(2) Present address: Nuclear Research Center Jülich, Federal Republic of Germany
Abstract:Summary Electrography and paper chromatography were combined to analyse rapidly metallic alloys in an almost non destructive technique. Using anodic dissolution the sample is applied on the start point of the chromatographic paper. Known ketones-HCl-water mixtures are usually used as solvents to analyse electrospots of different alloys and metal coatings and a separate electrospottest is recommended for Cr. Results of qualitative analysis of some steels, Cu–Ni, and Pb alloys are presented.
Keywords:Qualitative analysis  Spot tests  Paper chromatography  Metallic alloys  Electrography
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