Ruthenium-catalysed synthesis of tertiary amines from alcohols |
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| Authors: | M. Haniti S.A. Hamid |
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| Affiliation: | Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK |
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| Abstract: | Secondary amines have been converted into tertiary amines by reactions with primary alcohols. A catalytic system of [Ru(cymene)Cl2]2 with dppf has been shown to be effective for this transformation for a range of primary alcohols and secondary amines. The methodology has been applied to the one pot synthesis of Piribedil and other piperazine and morpholine-containing products. |
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