| 固体核磁法研究苯酚与聚4-乙烯基吡啶的相互作用 |
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| 引用本文： | 张静,陈英超,张赛晖,孙平川,袁直.固体核磁法研究苯酚与聚4-乙烯基吡啶的相互作用[J].高等学校化学学报,2009,30(4):818-820. |
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| 作者姓名： | 张静 陈英超 张赛晖 孙平川 袁直 |
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| 作者单位： | 功能高分子材料暨教育部重点实验室, 南开大学化学学院高分子研究所, 天津 300071;上海药明康德新药开发有限公司分析部, 上海 200131 |
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| 摘 要： | 采用高速魔角旋转(MAS)偶极滤波结合氘代稀释固体核磁技术, 研究了极性吸附分离材料聚乙烯吡啶与氘代苯酚之间的相互作用. 固体核磁结果表明, 聚乙烯吡啶与苯酚之间存在强的氢键作用, 与液体氢谱结果一致. 由MAS中水峰强度在吸附前后的变化揭示了苯酚部分置换了聚乙烯吡啶中的水, 且苯酚和聚乙烯吡啶氢键作用位点在靠近N的一端. 此种方法对于原位研究吸附剂的吸附机理以及新型吸附分离材料的设计具有重要的指导意义.
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| 关 键 词： | 氢键 偶极滤波魔角旋转NMR 氘稀释 小分子探针 |
| 收稿时间： | 2008-08-06 |
Interaction Between Phenol and Poly(4-vinylpyridine) Using Solid State NMR Method |
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| ZHANG Jing,CHEN Ying-Chao,ZHANG Sai-Hui,SUN Ping-Chuan,YUAN Zhi.Interaction Between Phenol and Poly(4-vinylpyridine) Using Solid State NMR Method[J].Chemical Research In Chinese Universities,2009,30(4):818-820. |
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| Authors: | ZHANG Jing CHEN Ying-Chao ZHANG Sai-Hui SUN Ping-Chuan YUAN Zhi |
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| Institution: | Key Laboratory of Functional Polymer Materials, Ministry of Education, Institute of Polymer Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China;Wuxi Pharmatech Co.Ltd, Shanghai 200131, China |
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| Abstract: | The interaction between phenol and poly(4-vinylpyprine) was investigated by means of the technique of dipolar filtered fast magic angle spinning(DF-MAS) combined with deuterium dilution 1H NMR.Experiment results reveal that strong hydrogen bond exist between phenol and poly(4-vinlypyridine),which is in good agreement with the data obtained from liquid state 1H NMR.Moreover,the difference in signals of water in MAS NMR disclosed that water was replaced by phenol in the binding with P4VP,and the interaction s... |
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| Keywords: | Hydrogen bond DF-MAS NMR Deuterium dilution Small molecule probe |
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