Saturable absorption dynamics of DODCI

The saturable absorption dynamics of DODCI in a femtosecond dye laser is studied theoretically. The N-isomer and P-isomer photoisomerization dynamics is included. The wavelength region between 570 nm and 650 nm is considered where the N-isomer and P-isomer absorption dynamics changes from short-wavelength to long-wavelength s₀-s₁ excitation. The slow saturable absorber DODCI shortens a circulating pulse in a laser oscillator down to femtosecond duration if the gain medium compensates the absorber losses. Fast local relaxation in the S₁ -state in the case of short-wavelength excitation and fast level refilling in the S₀ -state in the case of long-wavelength excitation facilitate the pulse shortening and the background signal suppression.