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The addition of (CF3SO2)2CHBr to vinylidene fluoride
Authors:Rolf W Winter
Institution:Department of Chemistry, Portland State University, Portland, OR 97207, USA
Abstract:It has been found that a mixture of (CF3SO2)2CH2 and (CF3SO2)2CBr2 can be used instead of (CF3SO2)2CHBr in the radical addition to H2Cdouble bond; length as m-dashCF2; the 1:1 and 1:2 adducts have been isolated and characterized. An improved synthesis of (CF3SO2)2CBr2 is also reported.
Keywords:Bis(trifluoromethanesulfonyl) derivatives  Vinylidene adducts with (CF3SO2)2CHBr
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