The formation of oxygen-containing perfluorocyclohexadien-1-yliodine tetrafluorides |
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| Authors: | Hermann-Josef Frohn Vadim V. Bardin |
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| Affiliation: | a Department of Chemistry, Inorganic Chemistry, University Duisburg-Essen, Lotharstr. 1, D-47048 Duisburg, Germany
b N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, SB RAS, Acad. Lavrentjev Ave. 9, 630090 Novosibirsk, Russia |
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| Abstract: | The electrophilic oxygenation of pentafluorophenyl iodo compounds C6F5IFn with iodine in different valencies (n = 0, 2, 4) using XeF2-H2O in HF allowed access to new organoiodine(V) compounds, namely isomeric oxopentafluorocyclohexadien-1-yliodine tetrafluorides, C6(O)F5IF4. |
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| Keywords: | Xenon difluoride Electrophilic oxygenation Organoiodine(V) tetrafluorides |
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